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ChemInform Abstract: Synthesis of Aryl Triolborates via Nickel-Catalyzed Borylation of Aryl Halides with 5-(tert-Butyldimethylsiloxymethyl)-5-methyl-1,3,2-dioxaborinane

Authors :
Shinji Watanabe
Miki Murata
Yosuke Sogabe
Takeshi Namikoshi
Source :
ChemInform. 43
Publication Year :
2012
Publisher :
Wiley, 2012.

Abstract

Reaction of the mono-Tbs protected triol (I) with borane dimethylsulfide generates the title compound which readily undergoes Ni-catalyzed borylation with various aryl iodides and bromides.

Details

ISSN :
09317597
Volume :
43
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........4529e0a48d0662780f62db53064fce01
Full Text :
https://doi.org/10.1002/chin.201232188