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Photothermally enhanced catalytic activity of partially aggregated gold nanoparticles
- Source :
- Journal of Nanoparticle Research. 14
- Publication Year :
- 2012
- Publisher :
- Springer Science and Business Media LLC, 2012.
-
Abstract
- This report describes the catalytic reduction of 4-nitrophenol (4-NP) using gold nanoparticles (GNPs) in aqueous solution upon exposure to a solar-simulated light. As monodispersed GNPs possess a strong but narrow absorption band in the visible areas, anisotropic/partially aggregated GNPs are designed to have a strong and wide absorption band across visible to near-infrared wavelengths of light. Given their strong and broad absorption properties, these partially aggregated GNPs exhibited slightly superior photothermally induced heating of the reaction medium (i.e., water) when compared to the monodispersed GNPs upon exposure to a solar-simulated light. Subsequently, the catalytic reduction of 4-NP to 4-aminophenol was examined in the presence of various GNPs with and without the irradiation of light. While the monodispersed GNPs exhibited a moderate increase in the reaction rates of 4-NP with the light irradiation, the partially aggregated GNPs afforded the notable enhancement of the reaction rate, presumably due to their higher photon-to-heat conversion efficiency.
- Subjects :
- Materials science
Aqueous solution
Energy conversion efficiency
Bioengineering
Nanotechnology
General Chemistry
Condensed Matter Physics
Photochemistry
Atomic and Molecular Physics, and Optics
Catalysis
Reaction rate
Absorption band
Colloidal gold
Modeling and Simulation
General Materials Science
Irradiation
Absorption (electromagnetic radiation)
Subjects
Details
- ISSN :
- 1572896X and 13880764
- Volume :
- 14
- Database :
- OpenAIRE
- Journal :
- Journal of Nanoparticle Research
- Accession number :
- edsair.doi...........44f9b68dcedb26b59d71e27f741fe623