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Benzoyl hydrazine-anchored graphene oxide as supercapacitor electrodes

Authors :
Jemini Jose
Sujin P. Jose
Sadasivan Shaji
P.B. Sreeja
S. Abinaya
Source :
Materials Chemistry and Physics. 256:123666
Publication Year :
2020
Publisher :
Elsevier BV, 2020.

Abstract

In this study, benzoyl-hydrazine anchored graphene oxide (BHGO) is synthesised using graphene oxide (GO) and benzoyl hydrazine (BH) via a simple, cost effective ultrasonic assisted chemical route. BH acted as a nitrogen source, reducing agent, and morphology modifier resulting in good electrochemical performance of BHGO. The supercapacitor behaviour of BHGO is investigated in different aqueous electrolytes and it exhibits a specific capacitance of 170 F g−1 at a current density of 1 A g−1 in 1 M H2SO4 and capacitive retention of 85% over 5000 cycles at 5 A g−1. This high performance is attributed to the enrichment of electroactive sites of GO through nitrogen moieties enhancing faradaic redox reactions and thereby the polarization at the electrode surface.

Details

ISSN :
02540584
Volume :
256
Database :
OpenAIRE
Journal :
Materials Chemistry and Physics
Accession number :
edsair.doi...........43cc553b8e4fc89b3a6268add1fa0fc8
Full Text :
https://doi.org/10.1016/j.matchemphys.2020.123666