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Benzoyl hydrazine-anchored graphene oxide as supercapacitor electrodes
- Source :
- Materials Chemistry and Physics. 256:123666
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- In this study, benzoyl-hydrazine anchored graphene oxide (BHGO) is synthesised using graphene oxide (GO) and benzoyl hydrazine (BH) via a simple, cost effective ultrasonic assisted chemical route. BH acted as a nitrogen source, reducing agent, and morphology modifier resulting in good electrochemical performance of BHGO. The supercapacitor behaviour of BHGO is investigated in different aqueous electrolytes and it exhibits a specific capacitance of 170 F g−1 at a current density of 1 A g−1 in 1 M H2SO4 and capacitive retention of 85% over 5000 cycles at 5 A g−1. This high performance is attributed to the enrichment of electroactive sites of GO through nitrogen moieties enhancing faradaic redox reactions and thereby the polarization at the electrode surface.
- Subjects :
- Supercapacitor
Materials science
Reducing agent
Graphene
Oxide
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Electrochemistry
01 natural sciences
Redox
0104 chemical sciences
law.invention
chemistry.chemical_compound
chemistry
Chemical engineering
law
Electrode
General Materials Science
0210 nano-technology
Polarization (electrochemistry)
Subjects
Details
- ISSN :
- 02540584
- Volume :
- 256
- Database :
- OpenAIRE
- Journal :
- Materials Chemistry and Physics
- Accession number :
- edsair.doi...........43cc553b8e4fc89b3a6268add1fa0fc8
- Full Text :
- https://doi.org/10.1016/j.matchemphys.2020.123666