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Photochemical transformations. Part XXVIII. Aryl azides as potential photosensitive protecting groups
- Source :
- Journal of the Chemical Society C: Organic. :721
- Publication Year :
- 1971
- Publisher :
- Royal Society of Chemistry (RSC), 1971.
-
Abstract
- The potential of certain aromatic azides as photosensitive protecting groups has been explored. With alkyl or acyl derivatives of β-(o-azidophenyl)ethyl alcohol photolysis yields indole and the corresponding alcohol or acid. Whereas o-azidobenzyl benzoate is photolysed in protic solvents to give polymers and little of the free acid, derivatives of 5-azido-4-hydroxymethyl-1-methoxynaphthalene are more efficiently photolysed with release of the protected group.
Details
- ISSN :
- 00224952
- Database :
- OpenAIRE
- Journal :
- Journal of the Chemical Society C: Organic
- Accession number :
- edsair.doi...........43698ebcb7f4195643df6ae75dff7aee