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An unexpected acyloin rearrangement and oxidation of a camphor derivative
- Source :
- Canadian Journal of Chemistry. 69:1315-1319
- Publication Year :
- 1991
- Publisher :
- Canadian Science Publishing, 1991.
-
Abstract
- The trimethylsiyl ether 7 derived in two steps from camphor underwent ring expansion via an acylion rearrangement to afford two products (8 and 9) when desilylation was attempted. Compound 9 was stable but 8 was oxidized in air to homocamphoric acid anhydride 11. Key words: camphor, acyloin rearrangement.
Details
- ISSN :
- 14803291 and 00084042
- Volume :
- 69
- Database :
- OpenAIRE
- Journal :
- Canadian Journal of Chemistry
- Accession number :
- edsair.doi...........434c186808c3ebaa476e4438eee8a80d
- Full Text :
- https://doi.org/10.1139/v91-195