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Photochemistry of pyridinium salts 2: Photobiscyclization of N-azomethine pyridinium derivatives

Authors :
Vladimir M. Feygelman
M. I. Knyazhanskii
Zvezdina Ella A
M. P. Zhdanova
Yakov R. Tymyanskii
Nadezhda I. Makarova
V. A. Kharlanov
Vitalii S. Orekhovskii
Source :
Journal of Photochemistry and Photobiology A: Chemistry. 54:91-97
Publication Year :
1990
Publisher :
Elsevier BV, 1990.

Abstract

The photobiscyclization reaction of N-azomethine pyridinium derivatives was investigated and the final and intermediate photoproducts were isolated. The first step of the reaction involves dihydro intermediate self-trapping by a 1,5-sigmatropic proton shift.

Details

ISSN :
10106030
Volume :
54
Database :
OpenAIRE
Journal :
Journal of Photochemistry and Photobiology A: Chemistry
Accession number :
edsair.doi...........433f557b41f9fb4d00061b6d53602401
Full Text :
https://doi.org/10.1016/1010-6030(90)87012-z