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Spectroscopic and Computational Assessment of Silicon’s Electrophilicity in Phosphinosilylium Cations

Authors :
Stephen J. Lee
Kathleen M. Riley
Michel R. Gagné
Andreas L. Wierschen
Source :
Organometallics. 39:1683-1687
Publication Year :
2020
Publisher :
American Chemical Society (ACS), 2020.

Abstract

An experimental method of determining the electrophilicity of silicon in phosphinosilylium cations is reported and compared to Djukic’s DFT method of computing relative intrinsic silylicity, Π. We ...

Details

ISSN :
15206041 and 02767333
Volume :
39
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........42de1657ca101b6c643aa0fee699da32
Full Text :
https://doi.org/10.1021/acs.organomet.0c00197