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Development of a Porous Catalytic Converter for Dehydrogenation of Cumene to α-Methylstyrene

Authors :
A. S. Fedotov
A. O. Kirillov
R. D. Kapustin
V. I. Uvarov
M. V. Tsodikov
Source :
Refractories and Industrial Ceramics. 61:355-359
Publication Year :
2020
Publisher :
Springer Science and Business Media LLC, 2020.

Abstract

A porous catalytically active membrane based on α-Al2O3 was synthesized. Powdered additives of the eutectic composition of magnesium oxide and silicon carbide were added to the initial corundum filler to synthesize a membrane framework with high open porosity and physical and mechanical characteristics that was pressed at 40 – 70 MPa followed by sintering in process combustion mode. Additives of Re2O7 andWO2 were added up to 4 mass% to the initial mixture by a simple technological method to impart catalytic properties to the synthesized membrane. Scientific foundations were developed for creating a technology for one-stage production of catalytically active ultraporous membrane converters effective for dehydrogenation of cumene to α-methylstyrene.

Details

ISSN :
15739139 and 10834877
Volume :
61
Database :
OpenAIRE
Journal :
Refractories and Industrial Ceramics
Accession number :
edsair.doi...........4219f65956f98a6b1304ece022e703bb
Full Text :
https://doi.org/10.1007/s11148-020-00486-0