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Optical properties of La1−xSrxVO3 (0 ≤ x ≤ 1) films grown on LSAT substrates using radio frequency sputtering deposition
- Source :
- Journal of Vacuum Science & Technology A. 40:013401
- Publication Year :
- 2022
- Publisher :
- American Vacuum Society, 2022.
-
Abstract
- La1−xSrxVO3 (0 ≤ x ≤ 1) films can be transparent conducting oxides such as n-type SrVO3 and p-type La2/3Sr1/3VO3 films. They also show a semiconductor-to-metal transition (SMT) near x = 0.2. The optical and electrical properties of La1−xSrxVO3 (0 ≤ x ≤ 1) films grown on (LaAlO3)0.3(Sr2AlTaO6)0.7 (LSAT) substrates using RF sputtering deposition were investigated. Resistivities of La1−xSrxVO3 showed SMT near x = 0.2. La1−xSrxVO3 films grown on LSAT substrates were found to have high crystallinity using θ−2θ scan and grazing incidence x-ray diffraction measurements. Dielectric functions of La1−xSrxVO3 films were measured using spectroscopic ellipsometry. The evolution of optical spectra of La1−xSrxVO3 films from LaVO3 to SrVO3 was compared to the electronic band structures as a function of Sr composition, which was either experimentally observed or theoretically calculated in the literature. With increasing Sr composition, the interband transition energies of O 2p to V 3d states near 4 eV changed linearly as a function of Sr content.
Details
- ISSN :
- 15208559 and 07342101
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- Journal of Vacuum Science & Technology A
- Accession number :
- edsair.doi...........41a87e610b564b9484b8f3674e938268