Back to Search
Start Over
ChemInform Abstract: Palladium-Catalyzed Sequential Reactions via Allene Intermediates for the Rapid Synthesis of Fused Polycyclic Pyrrole Derivatives
- Source :
- ChemInform. 41
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- In this paper, we report a novel sequential reaction sequence consisting of a series of processes including Sonogashira coupling, propargyl-allenyl isomerization, [3 + 2] cycloaddition, denitrogenation, and highly selective biradical coupling reaction, providing an efficient synthesis of fused polycyclic pyrrole derivatives. The reaction features one C-C bond and two C-N bonds formed to construct the pyrrole unit, together with two rings efficiently assembled in one stroke.
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 41
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........411d78557f5ae5815eaf7d64c917b6b7