ChemInform Abstract: Tungsten(0)- and Rhenium(I)-Catalyzed Tandem Cyclization of Acetylenic Dienol Silyl Ethers Based on Geminal Carbo-Functionalization of Alkynes

Authors :: Yuji Onizawa
Hiroyuki Kusama
Hokuto Yamabe
Yusuke Karibe
Nobuharu Iwasawa
Rie Imai
Source :: ChemInform. 42
Publication Year :: 2011
Publisher :: Wiley, 2011.
Abstract: Best results for the synthesis of bicyclo[3.3.0]octane derivatives by cyclization of siloxydienynes are achieved using rhenium(I) catalysts under photoirradiation conditions.

Subjects :: chemistry.chemical_compound
chemistry
Bicyclic molecule
Tandem
Geminal
Silylation
chemistry.chemical_element
General Medicine
Tungsten
Rhenium
Medicinal chemistry
Octane
Catalysis

Tools