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Group 6 metal carbonyl complexes of 1,5-diselena[5]ferrocenophane: Synthesis, characterization, crystallographic and electrochemical study

Authors :
Cheng-Yun Gu
Su Jing
Zhi-Wen Li
Wei Ji
Source :
Inorganica Chimica Acta. 363:1604-1606
Publication Year :
2010
Publisher :
Elsevier BV, 2010.

Abstract

The group 6 metal complexes of 1,5-diselena[5]ferrocenophane (L) have been prepared and characterized. The structures of [M(CO)4L] (M = Cr, Mo) show that L adopts the unusual meso-2 conformation. E1/2 of the 1,1′-ferrocenylene group in three complexes is much more positive than that of the “free” ligand L due to the electron donation from L to the M(CO)4 fragment.

Details

ISSN :
00201693
Volume :
363
Database :
OpenAIRE
Journal :
Inorganica Chimica Acta
Accession number :
edsair.doi...........40724f14725b9fa6a04e077946c701ad