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Non-planar phthalocyanines with Q-bands beyond 800 nm

Authors :
Terumi Ishiguro
Nagao Kobayashi
Takamitsu Fukuda
Source :
Tetrahedron Letters. 46:2907-2909
Publication Year :
2005
Publisher :
Elsevier BV, 2005.

Abstract

Free base and zinc 1,4,8,11,15,18,22,25-octa(p-methoxyphenyl) phthalocyanine have been synthesized. The Q-bands are located beyond 800 nm due to combined effects of red-shifts caused by ligand deformation and the electron-donating properties of the methoxy substituents. The phthalocyanines reported in this study could potentially replace naphthalocyanines as absorbers in the 800 nm region within practical applications.

Details

ISSN :
00404039
Volume :
46
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........3fc680838b1234df1549bb9ff315322f
Full Text :
https://doi.org/10.1016/j.tetlet.2005.02.134