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Synthesis of 2,5-Disubstituted Dihydrofuran-3(2H)-ones via [2,3]-Sigmatropic Rearrangement of Oxonium Ylides Generated from α-Oxo Gold Carbenes
- Source :
- Synlett. 24:2077-2080
- Publication Year :
- 2013
- Publisher :
- Georg Thieme Verlag KG, 2013.
-
Abstract
- Novel [2,3]-sigmatropic rearrangements of oxonium ylides generated from α-oxo gold carbenes were discovered. An ­efficient synthetic method of 2,5-disubstituted dihydrofuran-3(2H)-ones via gold-catalyzed intermolecular oxidation of the allyl homopropargyl ethers with N-oxide was developed. And the synthetic utility of the current method has been proved by concise formal synthesis of (±)-kumausallene.
Details
- ISSN :
- 14372096 and 09365214
- Volume :
- 24
- Database :
- OpenAIRE
- Journal :
- Synlett
- Accession number :
- edsair.doi...........3facd3bc62f391b3892fa9ce467ee1ea