Addition of sodium aluminum hydride to olefins

Authors :: V. K. Golubev
V. V. Gavrilenko
L. I. Zakharkin
Source :: Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 15:117-119
Publication Year :: 1966
Publisher :: Springer Science and Business Media LLC, 1966.
Abstract: 1. Sodium aluminum hydride reacts withα-olefins in the presence of such catalysts as AlR3, HAlR2, ClAlR2, AlX3, LiX, ZnX2, and LiAlH4 (X represents halogen), forming complexes with the structure NaAlR4. 2. In the oxidation of tetraalkyl complexes, alcohols are formed in high yields.

Subjects :: Chemistry
Metal carbonyl hydride
Sodium aluminum hydride
Inorganic chemistry
Halogen
General Chemistry
Catalysis

ISSN :: 15739171 and 05685230
Volume :: 15
Database :: OpenAIRE
Journal :: Bulletin of the Academy of Sciences, USSR Division of Chemical Science
Accession number :: edsair.doi...........3fa12fc3e511390280d03fe1cfbbd73c
Full Text :: https://doi.org/10.1007/bf00845849