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Altering polymer morphology by intense terahertz wave irradiation

Authors :
Masaya Nagai
Hiromichi Hoshina
Keigo Kawase
Goro Isoyama
Akinori Irizawa
Chiko Otani
Hal Suzuki
Source :
2016 41st International Conference on Infrared, Millimeter, and Terahertz waves (IRMMW-THz).
Publication Year :
2016
Publisher :
IEEE, 2016.

Abstract

In this presentation, we succeed in altering polymer morphology using terahertz (THz) wave irradiation. Pulsed THz waves generated by a free electron laser (FEL) were irradiated to a poly(3-hydroxybutylate) (PHB) / chloroform solution during solvent casting crystallization. Morphological observation shows the formation of micrometer-sized crystals via the THz wave irradiation. Further, a 10–20% increase in crystallinity is observed through analysis of the infrared (IR) absorption spectra.

Details

Database :
OpenAIRE
Journal :
2016 41st International Conference on Infrared, Millimeter, and Terahertz waves (IRMMW-THz)
Accession number :
edsair.doi...........3f5be507d492b93aaecc12f85014cde6
Full Text :
https://doi.org/10.1109/irmmw-thz.2016.7758906