Oxazoline Cyanocuprate: A New Approach to β-Carboxymethyl Functionalization of Enones

Authors :: Alcindo A. Dos Santos
Francisco A. de Marques
Paulo H. G. Zarbin
Giuliano C. Clososki
Fabio Simonelli
Alfredo R. M. de Oliveira
Source :: ChemInform. 34
Publication Year :: 2003
Publisher :: Wiley, 2003.
Abstract: This paper describes the preparation of a series of oxazoline cuprates by reaction of an oxazoline lithium anion with copper(I) salts: CuBr.DMS, Cul and CuCN in THF solution. The oxazoline cyanocuprate showed the best reactivity using enones as electrophiles.

Subjects :: chemistry.chemical_compound
chemistry
Electrophile
Polymer chemistry
Surface modification
chemistry.chemical_element
Organic chemistry
Lithium
Reactivity (chemistry)
General Medicine
Oxazoline
Copper

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