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An electron diffraction study of alkali chloride vapors
- Source :
- The Journal of Chemical Physics. 83:4418-4426
- Publication Year :
- 1985
- Publisher :
- AIP Publishing, 1985.
-
Abstract
- A study of monomers and dimers of the four alkali chlorides NaCl, KCl, RbCl, and CsCl in the vapor phase using the counting method of high energy electron diffraction is reported. Nozzle temperatures from 850-960 K were required to achieve the necessary vapor pressures of approximately 0.01 torr. Using harmonic calculations for the monomer and dimer 1 values, a consistent set of structures for all four molecules was obained. The corrected monomer distances reproduce the microwave values very well. The experiment yields information on the amount of dimer present in the vapor, and these results are compared with thermodynamic values.
Details
- ISSN :
- 10897690 and 00219606
- Volume :
- 83
- Database :
- OpenAIRE
- Journal :
- The Journal of Chemical Physics
- Accession number :
- edsair.doi...........3e61953ea14a1d31d9854da4b8221eba