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Modification of guanine residues in PNA-synthesis by PyBOP

Authors :
Stephan Pritz
Michael Bienert
Clementine Klemm
Yvonne Wolf
Source :
Tetrahedron Letters. 47:5893-5896
Publication Year :
2006
Publisher :
Elsevier BV, 2006.

Abstract

The phosphonium-type coupling reagent PyBOP, when applied to the synthesis of peptide nucleic acid (PNA) oligomers, was found to form O 4 -phosphonium compounds of the nucleobase guanine which can be converted into C 4 -modified guanine-derived PNAs by nucleophiles.

Details

ISSN :
00404039
Volume :
47
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........3ca76bf8a0949f0b2f728478bb498b5a
Full Text :
https://doi.org/10.1016/j.tetlet.2006.06.069