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Zwitterionic complexes arising from the reaction of tucked-in titanocenes with tris(pentafluorophenyl)borane
- Source :
- Inorganic Chemistry Communications. 8:222-226
- Publication Year :
- 2005
- Publisher :
- Elsevier BV, 2005.
-
Abstract
- Single tucked-in titanocene [Ti(η5-C5Me5)(η5:η1-C5Me4CH2)] adds to B(C6F5)3 to give the paramagnetic cationic complex [Ti(η5-C5Me5){η5-C5Me4CH2B(C6F5)3}] (1). Doubly tucked-in titanocene [Ti(η5-C5Me5){η3:η4-C5Me3(CH2)2}] reacts with B(C6F5)3 by one methylene group to give [Ti(η5-C5Me5){η5:η1-C5Me3(CH2)CH2B(C6F5)3}] (6). The crystal structure of 6 revealed that one hydrogen of the methylene group attached to boron agostically interacts with Ti(IV).
- Subjects :
- Hydrogen
Chemistry
Stereochemistry
Cationic polymerization
chemistry.chemical_element
Crystal structure
Inorganic Chemistry
chemistry.chemical_compound
Crystallography
X-ray crystallography
Materials Chemistry
Tris(pentafluorophenyl)borane
Physical and Theoretical Chemistry
Methylene
Boron
Titanium
Subjects
Details
- ISSN :
- 13877003
- Volume :
- 8
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........3ca4e702213ad0092c6c9f4f5387c1bc
- Full Text :
- https://doi.org/10.1016/j.inoche.2004.12.011