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Green polymer chemistry: One-pot, metal-free synthesis of macromonomer via direct polycondensation of lactic acid and its radical polymerization to graft and comb polymers
- Source :
- Polymer. 90:342-350
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- A new and simple method of one-pot two-stage poly(lactic acid) (PLA) macromonomer synthesis has been developed. The first stage of the reaction is a direct polycondensation of lactic acid (LA) without a catalyst to PLA, and the second stage is a ring-opening addition of PLA to glycidyl methacrylate (GMA) to afford a PLA macromonomer with a methacryloyl polymerizable group (GMA-Macro). Both reactions are performed consecutively in one pot. This method produced GMA-Macro with high functionality in high yields and thus far seems the simplest and probably the cheapest way to prepare PLA macromonomers. Furthermore, the method is metal-free, offering considerable advantages for biomedical and pharmaceutical applications. GMA-Macro has been shown to be useful for the preparation of PLA graft copolymers in solution or in miniemulsion and of PLA comb polymers in solution. LA is a biobased renewable feedstock. Thus, this method provides a good opportunity to conduct ‘green polymer chemistry’.
- Subjects :
- chemistry.chemical_classification
Glycidyl methacrylate
Condensation polymer
Materials science
Polymers and Plastics
Organic Chemistry
Radical polymerization
02 engineering and technology
Polymer
010402 general chemistry
021001 nanoscience & nanotechnology
Macromonomer
01 natural sciences
0104 chemical sciences
Lactic acid
Miniemulsion
chemistry.chemical_compound
chemistry
Polymer chemistry
Materials Chemistry
Copolymer
Organic chemistry
0210 nano-technology
Subjects
Details
- ISSN :
- 00323861
- Volume :
- 90
- Database :
- OpenAIRE
- Journal :
- Polymer
- Accession number :
- edsair.doi...........3c7f94a5d3c2b509c494e1ab1860f014