Recovery behaviors of acid-modified cement hydration material on phosphorous

Silicate cement hydration product is a promising phosphorus adsorption material. In view of the strong alkali characteristics of early hardening cement paste, this study adopted acid leaching method to modify and then investigated its phosphorus recovery performance. The results showed that acid modification could weaken the strong alkali property, nevertheless, it also lowered phosphorus removal efficiency. The decline of phosphorus recovery was closely related to the depletion of calcium source. By the fit calculation, it can be determined that the adsorption kinetics of modified material on phosphorus met the pseudo-second-order model. This was consistent with the behavior of unmodified material. Additionally, XRD analysis demonstrated that the phosphorus species enriched on the surface of modified material mainly consisted of hydroxyapatite and variscite, which was different from the brushite of unmodified material. Acid modification would provide much more aluminum sites on the adsorption of phosphorous.