Microwave-Assisted Suzuki-Miyaura Reactions with an Insoluble Pyridine-Aldoxime Pd-Catalyst

Authors :: Josef Messinger
Wladimir Solodenko
Uwe Schön
Andreas Kirschning
Anja Glinschert
Source :: Synlett. :1699-1702
Publication Year :: 2004
Publisher :: Georg Thieme Verlag KG, 2004.
Abstract: The preparation of a solid Pd(II)-precatalyst and its use in microwave-assisted Suzuki-Miyaura reactions in water is described. The precatalyst is obtained by treatment of 4-pyridine-aldoxime with Na 2 PdCl 4 and is insoluble in organic solvents as well as in water. Its robustness under microwave conditions and its insolubility allows simple reuse in 'teabags'.

Subjects :: chemistry.chemical_compound
chemistry
Robustness (computer science)
Organic Chemistry
Pyridine
Reuse
Microwave assisted
Combinatorial chemistry
Microwave
Catalysis

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