Constraints on element mobility associated with the conversion of granulite to eclogite along fractures in an anorthositic complex on Holsnoy, Norway

On Holsnoy, an island off the coast of Western Norway, an anorthositic complex metamorphosed to granulite facies was partially overprinted by a later eclogite facies metamorphism. Eclogite facies rocks (containing omphacite, garnet, kyanite and hydrous phases such as mica and zoisite) occur in shear zones of various scales and adjacent to veins. Previous studies of shear zones on Holsnoy reported evidence for substantial element mobility (Jamtveit et al., 1990; Mattey et al., 1994). In this work, we compare chemical compositions of granulite and its undeformed eclogitized equivalent adjacent to veins in locations where a single band of granulite can be traced and sampled as it approaches the vein. This tracing is crucial because the pre-granulite rocks cover a substantial compositional range, indicative of a petrologically variable protolith consisting of anorthosite, gabbro and jotunite. We analysed multiple core samples collected across nine separate granulite-eclogite transition zones located at veins in anorthositic, jotunitic and gabbroic protoliths for major and trace elements. For each transition, no compositional difference between the average granulite and average eclogite composition was found at the 90% confidence level except for LOI (loss on ignition), which was consistently significantly higher in the eclogite samples. Although not significant at the 90% confidence level for any single traverse, the average eclogite concentrations of SiO2 , Na2O, Cs, As and Br exceed the average granulite concentrations for eight or all nine of the traverses. For most traverses, statistical analysis of the data limits any gain of SiO2 in the eclogites to no more than a few relative per cent. Other than the introduction of volatile substances, presumably an H2O-rich fluid, eclogitization associated with vein formation was essentially isochemical.