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Intramolecular hydrogen bonding and conformation of a dipyrrolic derivative

Authors :
Angel Guzman
J. M. Muchowski
M R Van Calsteren
Edvige Galeazzi
J. L. Nava
K. Jankowski
Eduardo Díaz
Source :
Magnetic Resonance in Chemistry. 33:581-585
Publication Year :
1995
Publisher :
Wiley, 1995.

Abstract

The conformation of 1-phenyl-1-(1,2-dimethyl-5-pyrrolyl)-2-(2-methyl-5-benzoyl-1-pyrroly)ethanol, with characteristics of a molecular propeller, is stabilized by intramolecular hydrogen bonding as detected by 1H NMR, NOE difference experiments, 2D NMR, COSY, 13C NMR, HETCOR, HMBC and 1H NMR variable-temperature experiments.

Details

ISSN :
1097458X and 07491581
Volume :
33
Database :
OpenAIRE
Journal :
Magnetic Resonance in Chemistry
Accession number :
edsair.doi...........39fe499e11718fd6c765a264a1cec347