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Manganese(II)-Catalyzed Esterification of N-β-Hydroxyethyl­amides

Authors :
Shoko Akiyama
Yusuke Kita
Yuji Nishii
Kazushi Mashima
Source :
Synlett. 26:1831-1834
Publication Year :
2015
Publisher :
Georg Thieme Verlag KG, 2015.

Abstract

A catalyst system of manganese with 2,2-bipyridine for amide alcoholysis of N-β-hydroxyethylamides is described. This protocol enabled selective cleavage of the amide bond through a mechanism involving sequential N,O-acyl rearrangement and transesterification.

Subjects

Subjects :
Selective cleavage
chemistry.chemical_compound
chemistry
Selective reaction
Amide
Organic Chemistry
Polymer chemistry
chemistry.chemical_element
Peptide bond
Manganese
Transesterification
Catalysis

Details

ISSN :
14372096 and 09365214
Volume :
26
Database :
OpenAIRE
Journal :
Synlett
Accession number :
edsair.doi...........3913bd67887d2019e56ab118cb7b0366
Full Text :
https://doi.org/10.1055/s-0034-1380428
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