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Preparation and properties of AgNiF3 crystals

Authors :
T.H. Lee
F.T.J. Smith
R.M. Gluck
Source :
Materials Research Bulletin. 9:305-309
Publication Year :
1974
Publisher :
Elsevier BV, 1974.

Abstract

Transparent single crystals of AgNiF 3 up to 3 mm on an edge have been grown by slow cooling from AgF flux. The crystals are tetragonal, space group D 6 4 -p4 2 2 1 2, with cell constants a = 5.56 A and c = 7.86 A . The material has an optical absorption spectrum typical of divalent nickel in octahedral coordination with fluoride ions. A noncollinear antiferromagnetic transition at 197°K is observed.

Details

ISSN :
00255408
Volume :
9
Database :
OpenAIRE
Journal :
Materials Research Bulletin
Accession number :
edsair.doi...........390ada16685920f3a2b6c3260c558dc6