Hydrochalcogenation of activated olefines. Synthesis of functionalized dialkylchalcogenides

Authors :: Rogério A. Gariani
Jefferson L. Princival
Fabiano K. Zinn
João V. Comasseto
Alcindo A. Dos Santos
Source :: Journal of Organometallic Chemistry. 693:2929-2936
Publication Year :: 2008
Publisher :: Elsevier BV, 2008.
Abstract: Alkanethiols, selenols and tellurols are generated in situ by reaction of elemental sulfur, selenium and tellurium with commercial alkyllithiums, followed by reaction with deoxygenated water. The alkanechalcogenols react in situ with activated olefins in a Michael-type addition reaction.

Subjects :: inorganic chemicals
In situ
Addition reaction
Stereochemistry
Organic Chemistry
chemistry.chemical_element
Biochemistry
Sulfur
Inorganic Chemistry
chemistry
Materials Chemistry
Organic chemistry
Physical and Theoretical Chemistry
Tellurium
Selenium

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