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Pyrolysis products in ion/molecule reactions. I. Alcohols

Authors :
Gary Caldwell
John E. Bartmess
Source :
International Journal of Mass Spectrometry and Ion Physics. 40:269-274
Publication Year :
1981
Publisher :
Elsevier BV, 1981.

Abstract

The (M — 3)− ions in the negative chemical ionization spectra of alcohols in an ICR spectrometer are shown to arise from pyrolysis of the neutral alcohol on various hot surfaces in the instrument. Carbonyl compounds are formed, followed by deprotonation. Similar reactions are observed for alkyl nitrites and peroxides.

Subjects

Subjects :
chemistry.chemical_compound
Chemical ionization
Deprotonation
Spectrometer
Chemistry
Inorganic chemistry
Molecule
Alcohol
Alkyl nitrites
Photochemistry
Pyrolysis
Spectroscopy
Ion

Details

ISSN :
00207381
Volume :
40
Database :
OpenAIRE
Journal :
International Journal of Mass Spectrometry and Ion Physics
Accession number :
edsair.doi...........389a615fcbaf6977c36bf691ecacd992
Full Text :
https://doi.org/10.1016/0020-7381(81)80091-5
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