ChemInform Abstract: TIPSOTf-Promoted Tandem Reaction Through Rearrangement of Epoxides into Aldehydes with Selective Alkyl Migration Followed by Prins-Type Cyclization to Cyclopentanes

Authors :: Takeshi Kodama
Takeshi Tanaka
Yoshimitsu Tachi
Yoshiki Morimoto
Shingo Harada
Source :: ChemInform. 43
Publication Year :: 2012
Publisher :: Wiley, 2012.
Abstract: The intermediate aldehydes undergo direct cyclization to the ajacent isoprenyl substituent to give cyclopentane derivatives with moderate diastereoselectivity.

Subjects :: chemistry.chemical_classification
chemistry.chemical_compound
Cyclopentanes
chemistry
Cascade reaction
Substituent
Organic chemistry
General Medicine
Cyclopentane
Alkyl

Full Text Access

Tools