Photoisomerization of methylthiirane radical cations in freonic matrices at 77 K

Authors :: Mikhail Ya. Melnikov
Oleg I. Gromov
Ivan D. Sorokin
Vladimir I. Pergushov
Irina S. Zharinova
Source :: Mendeleev Communications. 27:479-481
Publication Year :: 2017
Publisher :: Elsevier BV, 2017.
Abstract: A reversible photochemical transition between an open pseudoallylic form and a cyclic form has been discovered for methylthiirane radical cations in the matrices of CFCl3 and CF3CCl3 at 77 K.

Subjects :: Photoisomerization
010405 organic chemistry
Chemistry
Methylthiirane
General Chemistry
010402 general chemistry
Photochemistry
01 natural sciences
0104 chemical sciences
Cyclic form

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