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Spectroscopic characterization of Sm3+ in La3Ga5.5Ta0.5O14 single crystals
- Source :
- Journal of Alloys and Compounds. 610:50-54
- Publication Year :
- 2014
- Publisher :
- Elsevier BV, 2014.
-
Abstract
- La 3 Ga 5.5 Ta 0.5 O 14 single crystals with nominal Sm 3+ concentrations of 0.5 at.% and 3 at.% were grown by the Czochralski method from iridium crucibles. Examination of chemical composition of manufactured crystals revealed that actual Sm 3+ concentrations are 0.27 at.% and 1.96 at.%, respectively. Spectroscopic measurement encompassed acquisition of absorption spectra, luminescence spectra and luminescence decay curves at temperatures between 5 K and 300 K. Analysis of room temperature absorption spectra in the framework of the Judd–Ofelt treatment made it possible to determine radiative transition rates branching ratio values related to the 4 G 5/2 luminescence of Sm 3+ ions. Crystal field splitting of Sm 3+ multiplets involved in luminescence phenomena was inferred from absorption and emission spectra recorded at 5 K. It was found that absorption and luminescence transitions exhibit strong anisotropy and their intensities for σ-polarized spectra is higher by a factor of two roughly than those for π-polarized spectra. Observed strong inhomogeneous broadening of spectral bands was attributed to certain structural disorder of the host resulting from the substitution of octahedrally coordinated Ga 3+ ions by Ta 5+ ions. It follows from calculated and experimental values of luminescence branching ratio that about 80% of excitation energy of the 4 G 5/2 metastable level is converted to visible luminescence distributed into three bands peaking at 550 nm, 600 nm and 646 nm. It was concluded that the La 3 Ga 5.5 Ta 0.5 O 14 :Sm 3+ system is promising for application as an orange–red emitting phosphor and deserves further investigation aimed at assessing its ability to show yellow laser emission.
- Subjects :
- Materials science
Absorption spectroscopy
Mechanical Engineering
Metals and Alloys
Analytical chemistry
chemistry.chemical_element
Phosphor
Spectral line
chemistry
Mechanics of Materials
Crystal field theory
Materials Chemistry
Emission spectrum
Iridium
Luminescence
Absorption (electromagnetic radiation)
Subjects
Details
- ISSN :
- 09258388
- Volume :
- 610
- Database :
- OpenAIRE
- Journal :
- Journal of Alloys and Compounds
- Accession number :
- edsair.doi...........364ad3ba87efb5e3476360e3d8a4e91a