ChemInform Abstract: Pd-Catalyzed Regioselective Activation of gem-Difluorinated Cyclopropanes: A Highly Efficient Approach to 2-Fluorinated Allylic Scaffolds

Authors :: Yao Fu
Jun Xu
Qianqian Lu
Ebrahim-Alkhalil M. A. Ahmed
Bin Xiao
Chu-Guo Yu
Yun-Long Wang
Source :: ChemInform. 46
Publication Year :: 2015
Publisher :: Wiley, 2015.
Abstract: A variety of 2-fluoroallylic amines, ethers, esters, and alkylation products are efficiently obtained with high Z-selectivity through regioselective activation of gem-difluorinated cyclopropanes induced by C—C bond cleavage.

Subjects :: Allylic rearrangement
endocrine system diseases
Chemistry
Regioselectivity
General Medicine
Alkylation
Combinatorial chemistry
Bond cleavage
Catalysis

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