Cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with olefins in the presence of the second-generation Grubbs catalyst

Authors :: Bogdan Marciniec
Cezary Pietraszuk
Helmut Fischer
Source :: Tetrahedron Letters. 44:7121-7124
Publication Year :: 2003
Publisher :: Elsevier BV, 2003.
Abstract: The efficient cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with various olefins is described. High yields and selectivities were obtained when styrene, 1-hexene, and selective functional allyl derivatives were used as the olefins.

Subjects :: Grubbs' catalyst
chemistry.chemical_compound
chemistry
Organic Chemistry
Drug Discovery
Polymer chemistry
Polar effect
chemistry.chemical_element
Metathesis
Biochemistry
Styrene
Ruthenium

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