Chemistry in Shocked Interstellar Gas

In its passage through the interstellar gas, a shock imposes massive and irreversible changes on the chemical composition of the gas. The synthesis of molecules from atoms and atomic ions can be highly efficient behind non-dissociative (i.e. slow) shocks. Results of kinetic calculations behind non-dissociative shocks are reviewed here, with emphasis given to the dependence of the postshock molecular composition on initial cloud properties. It is shown that a dense cloud shock can convert essentially all neutral atoms into various molecules. Even in diffuse and unshielded regions, a variety of molecules can attain a high abundance behind shocks. The suggestion that the widespread diffuse cloud species CH+ is shock synthesized is critically examined in the light of new calculations.