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Synthesis and characterization of a mixed-valence hexadecavanadate cluster with half-open framework
- Source :
- Inorganic Chemistry Communications. 12:219-222
- Publication Year :
- 2009
- Publisher :
- Elsevier BV, 2009.
-
Abstract
- A new mixed-valence hexadecavanadate cluster compound, (Me2NH2)4[H6V16O42(SO4)] · 8H2O (1), has been synthesized via an efficient method in organic media. The hollow cluster shell of 1, with a sulfate ion locating in its centre, exhibits four large eight-membered –O–V–O–V– rings on its surface, which makes the cluster into a half-open structure distinguished from the common hollow clusters built up with closed surfaces. The intense blue luminescence of 1 in solution state is scarcely reported for the polyoxometalate clusters.
Details
- ISSN :
- 13877003
- Volume :
- 12
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........344490e4602a1bc97b183d3a94a78ba7
- Full Text :
- https://doi.org/10.1016/j.inoche.2008.12.021