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Germanium nanoparticles supported by 3D ordered macroporous nickel frameworks as high-performance free-standing anodes for Li-ion batteries
- Source :
- Chemical Engineering Journal. 354:616-622
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- Germanium-based materials are gaining increasing attention as promising anodes for Li-ion batteries (LIBs) due to their high specific capacity, good cycling stability and excellent rate performance. Similarly to Si, Ge-based anodes undergo a huge volume expansion and contraction during Li intercalation and deintercalation, causing a rapid and irreversible capacity decay. In this work, Ge nanoparticles are uniformly attached to a 3D ordered macroporous (3DOM) Ni framework (Ge/3DOM-Ni) via a facile drop-coating technique in order to address the volume expansion and stability issues plaguing Ge anodes. The 3D ordered macroporous Ni frameworks with high porosity act not only as highly conductive current collectors but also as a robust porous support for the formation of a thin layer of Ge nanoparticles. The three-dimensional porous network facilitates the penetration of the electrolyte and lithium ions. The possible alloy interface generated among the Ge nanoparticles and Ni framework during the calcination process ensures good electric contact among the nanoparticles and the 3D ordered macroporous Ni framework. When used as self-supporting binder-free anodes for lithium ion batteries, the Ge/3DOM-Ni electrode shows high rate performance and excellent structural and cycling stability. This work provides a facile and effective strategy for improving the electrochemical performance of Ge-based anodes.
- Subjects :
- Materials science
General Chemical Engineering
Alloy
Nanoparticle
chemistry.chemical_element
Germanium
02 engineering and technology
Electrolyte
engineering.material
010402 general chemistry
Electrochemistry
01 natural sciences
Industrial and Manufacturing Engineering
law.invention
law
Environmental Chemistry
Calcination
Porosity
General Chemistry
021001 nanoscience & nanotechnology
0104 chemical sciences
Anode
Chemical engineering
chemistry
engineering
0210 nano-technology
Subjects
Details
- ISSN :
- 13858947
- Volume :
- 354
- Database :
- OpenAIRE
- Journal :
- Chemical Engineering Journal
- Accession number :
- edsair.doi...........33e8c2389b39188ff10fdfdafc33caf7