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Quantitative phase analysis of boron nitride nanotubes using Rietveld refinement
- Source :
- Journal of Physics D: Applied Physics. 38:1127-1131
- Publication Year :
- 2005
- Publisher :
- IOP Publishing, 2005.
-
Abstract
- Crystalline boron nitride nanotubes (BNNTs) with an average outer diameter of about 40 nm and several micrometres in length were synthesized by chemical vapour deposition from boron and magnesium oxide. Rietveld refinement and 11B solid-state nuclear magnetic resonance (NMR) spectroscopy were employed to quantitatively determine the phase of synthesized BNNTs. The structural parameters for the BNNTs were determined by Rietveld refinement against powder x-ray diffraction data with a model based on the results of NMR analysis. The final weighted R-factor, Rwp, was 6.08% and the goodness-of-fit indicator, S (= Rwp/Re), was 1.52. The BNNTs consisted of hexagonal BN, rhombohedral BN and MgO with refined weight fractions of 76.3%, 21.2% and 2.5%, respectively.
- Subjects :
- Materials science
Acoustics and Ultrasonics
Rietveld refinement
Magnesium
Analytical chemistry
chemistry.chemical_element
Chemical vapor deposition
Crystal structure
Condensed Matter Physics
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Crystallography
chemistry.chemical_compound
chemistry
Boron nitride
Phase (matter)
Spectroscopy
Boron
Subjects
Details
- ISSN :
- 13616463 and 00223727
- Volume :
- 38
- Database :
- OpenAIRE
- Journal :
- Journal of Physics D: Applied Physics
- Accession number :
- edsair.doi...........32f27a621fe392092bfed0f33cbff8d9