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Functionalization of RhIII–Me Bonds: Use of 'Capping Arene' Ligands to Facilitate Me–X Reductive Elimination
- Source :
- Organometallics. 40:1889-1906
- Publication Year :
- 2021
- Publisher :
- American Chemical Society (ACS), 2021.
-
Abstract
- We show how to improve the yield of MeX from CH4 activation catalysts from 12% to 90% through the use of “capping arene” ligands. Four (FP)RhIII(Me)(TFA)2 {FP = “capping arene” ligands, including 8...
Details
- ISSN :
- 15206041 and 02767333
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- Organometallics
- Accession number :
- edsair.doi...........3286a8c995c339ce6574c1aff9e6787e