Satellite dielectronic spectra created from autoionizing 2lnl' and 1s2lnl' states with n = 4–5

The relative intensities of dielectronic satellite lines determined by radiative transition probabilities and autoionization rates are calculated for the transitions 2lnl' – 1snl'', 2lnl' – 1s2l (n = 4–5, l' = 0–3, l'' = 0–3, l = 0–1) in He-like ions and for the transitions 1s2lnl' – 1s2nl'', 1s2lnl' – 1s22l (n = 4–5, l' =0–3, l'' = 0–3, l = 0–1) in Li-like ions, for all Z = 5–54, using the perturbation theory method (Z-expansion). Relativistic effects are taken into account using the Breit–Pauli operators. The asymptotic dependence on n of the energy matrix is discussed for 2lnl' and 1s2lnl' autoionizing states. The intermediate coupling coefficients obtained after diagonalization of the energy matrices are also studied. It was observed that these coefficients change very sharply with n and Z due to a redistribution of the contributions of relativistic and correlation effects. As a result, all other atomic characteristics (radiative and nonradiative transition rates, branching ratios, and relative intensity factor) display nonmonotonic Z- and n-dependencies with maxima and minima. PACS Nos.: 32.80D, 31.20G, 31.30J, 31.50