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catena-Poly[[[(4'-phenyl-2,2':6',2'-terpyridine-κ3N)copper(II)]-μ-terephthalato-κ2O:O′] terephthalic acid]

Authors :
Dan Li
Seik Weng Ng
Ye-Gao Yin
Qi-Dong Tu
Xiao-Chun Huang
Source :
Acta Crystallographica Section E Structure Reports Online. 61:m103-m105
Publication Year :
2004
Publisher :
International Union of Crystallography (IUCr), 2004.

Abstract

The title compound, [Cu(C8H4O4)(C21H15N3)]·C8H6O4, consists of polymeric chains in which the terpyridine heterocycle chelates to the Cu atom in an N,N′,N′′-tridentate manner; the Cu atoms are also covalently bonded through the two singly-bonded carboxyl O atoms of the dicarboxyl­ate dianions to give rise to a chain structure. An additional terephthalic acid molecule is hydrogen bonded to the chains. The asymmetric unit contains halves of two different half-molecule terephthalate ions; in each case, the complete ions are generated by inversion symmetry.

Details

ISSN :
16005368
Volume :
61
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........319910a593cb06968e21fbefe6a2cc1d