Back to Search
Start Over
catena-Poly[[[(4'-phenyl-2,2':6',2'-terpyridine-κ3N)copper(II)]-μ-terephthalato-κ2O:O′] terephthalic acid]
- Source :
- Acta Crystallographica Section E Structure Reports Online. 61:m103-m105
- Publication Year :
- 2004
- Publisher :
- International Union of Crystallography (IUCr), 2004.
-
Abstract
- The title compound, [Cu(C8H4O4)(C21H15N3)]·C8H6O4, consists of polymeric chains in which the terpyridine heterocycle chelates to the Cu atom in an N,N′,N′′-tridentate manner; the Cu atoms are also covalently bonded through the two singly-bonded carboxyl O atoms of the dicarboxyl­ate dianions to give rise to a chain structure. An additional terephthalic acid molecule is hydrogen bonded to the chains. The asymmetric unit contains halves of two different half-molecule terephthalate ions; in each case, the complete ions are generated by inversion symmetry.
Details
- ISSN :
- 16005368
- Volume :
- 61
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi...........319910a593cb06968e21fbefe6a2cc1d