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Synthesis, separation, and identification of 4-bromoadamantan-2-one stereoisomers
- Source :
- Collection of Czechoslovak Chemical Communications. 45:2670-2674
- Publication Year :
- 1980
- Publisher :
- Institute of Organic Chemistry & Biochemistry, 1980.
-
Abstract
- A one-step synthesis of mixture of stereoisomers of 4-bromoadamantan-2-one based on the reaction of adamantan-2-one with hydroxylamine hydrochloride in hydrobromic acid is described. The pure stereoisomers were isolated by elution chromatography on silica gel, and their NMR spectra with the Eu(FOD)3 shift reagent, mass spectra, IR spectra, and dipole moments were measured.
Details
- ISSN :
- 12126950 and 00100765
- Volume :
- 45
- Database :
- OpenAIRE
- Journal :
- Collection of Czechoslovak Chemical Communications
- Accession number :
- edsair.doi...........31946387f49186439b48531f16f88d68