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In situ acyl triflates ace it
- Source :
- Nature Chemistry. 10:116-117
- Publication Year :
- 2018
- Publisher :
- Springer Science and Business Media LLC, 2018.
-
Abstract
- A simple palladium catalyst has mediated the facile formation of aroyl triflates — an extremely reactive class of electrophiles. These intermediates, generated in situ, enable the Friedel–Crafts acylation of traditionally unreactive arenes, addressing a significant gap in C–H carbonylation methodology.
Details
- ISSN :
- 17554349 and 17554330
- Volume :
- 10
- Database :
- OpenAIRE
- Journal :
- Nature Chemistry
- Accession number :
- edsair.doi...........2eef74236a65f26d98393fff66669f74