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Synthesis, characterization and use of a new tethered Rh(III) complex in asymmetric transfer hydrogenation of ketones
- Source :
- Catalysis Communications. 62:95-99
- Publication Year :
- 2015
- Publisher :
- Elsevier BV, 2015.
-
Abstract
- A new Rh(III) complex containing the TsDPEN ligand and an η6-arene connected through a carbon tether is reported. The asymmetric transfer hydrogenation of a series of ketones catalyzed by this complex using the formic acid/triethylamine system provided the corresponding alcohols with complete conversions and a high level of enantioselectivity.
- Subjects :
- chemistry.chemical_classification
Ketone
Chemistry
Formic acid
Process Chemistry and Technology
Enantioselective synthesis
chemistry.chemical_element
Noyori asymmetric hydrogenation
General Chemistry
Transfer hydrogenation
Combinatorial chemistry
Catalysis
Rhodium
chemistry.chemical_compound
Organic chemistry
Triethylamine
Subjects
Details
- ISSN :
- 15667367
- Volume :
- 62
- Database :
- OpenAIRE
- Journal :
- Catalysis Communications
- Accession number :
- edsair.doi...........2ed50eff8712d2a388188e1c86dc6551
- Full Text :
- https://doi.org/10.1016/j.catcom.2015.01.012