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Transition metal complexes of the cis-dithiosquaramide ligand family

Authors :
Fusao Takusagawa
Greg R. Frauenhoff
Daryle H. Busch
Source :
Inorganic Chemistry. 31:4002-4007
Publication Year :
1992
Publisher :
American Chemical Society (ACS), 1992.

Abstract

3,4-Bis(alkylamino)-3-cyclobuten-1,2-dithiones (cis-dithiosquaramides, LH 2 ) react with divalent metal acetates to give neutral 2:1 complexes of the general formula M II (LH) 2 -xH 2 O (M II =Ni, Cu, Pd). The ligands bind in a didentate S 2 Cashion Corming a square planar M II S 4 coordination sphere.

Details

ISSN :
1520510X and 00201669
Volume :
31
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........2d8354d2545163ad414f6a67d1edecb7
Full Text :
https://doi.org/10.1021/ic00045a027