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Study on the preparation of active support and multi-porous supported catalyst

Authors :
Axel Schulz
Tran Trong Hoa
Nguyen Trung Kien
Hendrik Kosslick
Nguyen H. Hao
Bui Thi Hai Linh
Dang T. Phuong
Vu Anh Tuan
Publication Year :
2010
Publisher :
Elsevier, 2010.

Abstract

The preparation of improved catalytic materials based on natural diatomite is reported. Aluminum incorporation by an atomic implantation methods yields supports with enhanced acidity. Nano-zeolite Y supported diatomite composite materials with a multimodao distribution of interconnected micro- meso- and macro pores were obtained by in situ crystallization. Materials were characterized by XRD, TEM, NH 3 -TPD and textural studies using nitrogen adsorption / desorption measurements. The catalytic performance was tested in the cracking of a heavy petroleum residue. The results show, that diatomite due to its large pores is a superior support for the preparation of supported catalysts for the cracking of heavy oil fraction containing bulky molecules. Atomic implantation of aluminum yields catalysts of the same catalytic performance as loading with acidic nano-sized zeolite HY.

Details

Database :
OpenAIRE
Accession number :
edsair.doi...........2d13f9881aa6065bbd4126a906a9d2ba
Full Text :
https://doi.org/10.1016/s0167-2991(10)75094-1