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An improved synthesis of chiral diols via the asymmetric catalytic hydrogenation of prochiral diones

Authors :
Qing-Hua Fan
Albert S. C. Chan
Chi-Hung Yeung
Source :
Tetrahedron: Asymmetry. 8:4041-4045
Publication Year :
1997
Publisher :
Elsevier BV, 1997.

Abstract

The rates of the asymmetric hydrogenation of prochiral diketones catalyzed by Ru(BINAP) catalysts were substantially accelerated in the presence of small amounts of a strong acid.

Details

ISSN :
09574166
Volume :
8
Database :
OpenAIRE
Journal :
Tetrahedron: Asymmetry
Accession number :
edsair.doi...........2cedeaddd59b06a2b09c26b7f0a93b09