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Profiles of the Distribution of Atoms in the Nitrous Oxide–acetylene Flame

Authors :
Kitao Fujiwara
Keiichiro Fuwa
Hiroki Haraguchi
Source :
Bulletin of the Chemical Society of Japan. 48:857-862
Publication Year :
1975
Publisher :
The Chemical Society of Japan, 1975.

Abstract

The distributions of neutral atoms in the nitrous oxide–acetylene flame have been measured by nebulizing aquo ions of the following sixteen elements into the flame; cadmium, nickel, zinc, copper, lead, cobalt, manganese, iron, chromium, molybdenum, calcium, tin, gallium, indium, titanium, and boron. The distributions have been figured on the response surfaces on which the changes in distribution are expressed as functions of the flame height and the acetylene flow rate. The response surfaces for the temperature and the OH radical were also investigated. The response surfaces for the atomic absorptions of the elements can be related to the thermodynamic properties of the oxides of the elements. The results have then been used for the discussion of the atomization processes of the elements in the flame. In addition, the sensitivities of absorption spectrometry in the nitrous oxide–acetylene flame have been compared to those in the air–acetylene flame.

Details

ISSN :
13480634 and 00092673
Volume :
48
Database :
OpenAIRE
Journal :
Bulletin of the Chemical Society of Japan
Accession number :
edsair.doi...........2c3ee813bd1541456e3c0e6d9881e855
Full Text :
https://doi.org/10.1246/bcsj.48.857