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C–H bond activations by the HO˙/(Salophent-Bu)Co(<scp>ii</scp>) radical pair generated via homolysis of a terminal Co(<scp>iii</scp>)–OH bond

Authors :
Jia Zhang
Songyi Li
Huayi Fang
Source :
Chemical Communications. 59:3245-3248
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

The reactive HO˙/(Salophent-Bu)Co(ii) radical pair was generated via a terminal Co(iii)–OH bond homolysis in hydroxocobalt(iii) complexes. Based on this process, C–H bond activations in different substrates were achieved under ambient conditions.

Details

ISSN :
1364548X and 13597345
Volume :
59
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi...........2bf55e5d7e72e3a0aafafb40c11db780
Full Text :
https://doi.org/10.1039/d3cc00146f