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Synthesis and Characterization of the New Lead Strontium Germanate PbSrGeO4
- Source :
- Zeitschrift für Naturforschung B. 69:845-850
- Publication Year :
- 2014
- Publisher :
- Walter de Gruyter GmbH, 2014.
-
Abstract
- The new lead strontium germanate PbSrGeO4 was synthesized by a high-temperature solid-state reaction of lead(II) oxide, strontium carbonate, and germanium(IV) oxide at a temperature of 900 °C in a platinum crucible. The compound crystallizes in the orthorhombic space group P212121 (no. 19) being isotypic to the structure of BaNdGaO4 [1]. The primitive cell contains four formula units with lattice parameters of a = 995:40(2), b = 732:44(2), c = 599:42(2) pm, V = 437:02(2)Å3, and residuals of R1 = 0:0385 and wR2 = 0:0997 for all data. The main structural element of PbSrGeO4 is an isolated [GeO4]4- tetrahedron. A circular arrangement of six of these [GeO4]4- tetrahedra leads to the formation of large channels along b in which the strontium cations are eightfold coordinated by oxygen atoms. The lead cations are coordinated by three oxygen atoms, and with a lone pair of electrons they show a pseudo-tetrahedral coordination. Next to the structural investigations, PbSrGeO4 was characterized by Raman-spectroscopic investigations and DFT calculations.
Details
- ISSN :
- 18657117 and 09320776
- Volume :
- 69
- Database :
- OpenAIRE
- Journal :
- Zeitschrift für Naturforschung B
- Accession number :
- edsair.doi...........2aeece0cd1148ede4231a8fafd809bc7